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PCC Admixtures

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Admixtures are the ingredients in PCC other than aggregate, portland cement and water. Typically, an admixture is added to alter a specific PCC property such as workability, setting time, strength or durability.

Table 1.
TypeDesired EffectMaterial
AcceleratorsAccelerate setting and early strength developmentCalcium chloride, triethanolamine, sodium thiocyanate, calcium formate, calcium nitrite, calcium nitrate
Air detrainersDecrease air contentTributyl phosphate, dibutyl phthalate, octyl alcohol, water-insoluble esters of carbonic and boic acid, silicones
Air-entrainingImprove durability in environments of freeze-thaw, deicers, sulfate and alkali reactivityImprove workabilitySalts of wood resins, lignin, petroleum acids, proteinaceous material or sulfonated hydrocarbonsSome synthetic detergentsFatty and resinous acids and their saltsAlyklbenzene sulfonates
Alkali-reactivity reducersReduce alkali-reactivity expansionPozzolans, blast-furnace slag, salts of lithium and barium, air-entraining agents
BondingIncrease bond strengthRubber, polyvinyl chloride, polyvinyl acetate, acrylics, butadienestyrene copolymers
Corrosion inhibitorsReduce steel corrosion activity in a chloride environmentCalcium nitrite, sodium nitrite, sodium benzoate, certain phosphates or flurosilicates, fluroaluminates
Damp proofingRetard moisture penetration into dry PCCSoaps of calcium or ammonium stearate or oleateButyl stearatePetroleum products
Cementitious MineralsHydraulic propertiesPartial cement replacementGround granulated blast-furnace slagNatural cementHydraulic hydrated lime
Natural pozzolansPozzolonic activityImprove workability, plasticity, sulfate resistanceReduce alkali reactivity, permeability, heat of hydrationPartial cement replacementFillerDiatomaceous earth, opaline cherts, clays, shales, volcanic tuffs, pumicitesFly ash (classes C and F)Silica fume
Inert mineralsImprove workabilityFillerMarble, dolomite, quartz, granite
Permeability reducersReduce permeabilitySilica fume, fly ash, ground slag, natural pozzolans, water reducers, latex
Pumping aidsImprove pumpabilityOrganic and synthetic polymersOrganic flocculentsOrganic emulsions of paraffin, coal tar, asphalt, acrylicsBentonite and pyrogenic silicasNatural pozzolansFly ashHydrated lime
RetardersRetard setting timeLignin, borax, sugars, tartaric acid and salts
Superplasticizers (high-range water reducers)Reduce water-cement ratio by a minimum of 12%Increase workability at low water-cement ratiosSulfonated melamine formaldehyde condensatesSulfonated naphthalene formaldehyde condensatesLignosulfonates
Water reducerReduce water demand by a minimum of 5%LignosulfonatesHydroxylated carboxylic acidsCarbohydrates
Workability agentsImprove workabilityAir-entraining admixturesCementitious materials, natural pozzolans and inert minerals (except silica fume)

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APA

Pavement Interactive. (2026, November 1). PCC admixtures. HeadLight. Retrieved [the date you read it], from https://pavementinteractive.org/reference-desk/design/mix-design/pcc-admixtures/

ASCE

Pavement Interactive. (2026). “PCC Admixtures.” HeadLight, <https://pavementinteractive.org/reference-desk/design/mix-design/pcc-admixtures/> ([the date you read it]).

BibTeX

@misc{pavint-pcc-admixtures,
  author = {{Pavement Interactive}},
  title = {PCC Admixtures},
  year = {2026},
  publisher = {HeadLight},
  howpublished = {\url{https://pavementinteractive.org/reference-desk/design/mix-design/pcc-admixtures/}},
  note = {Accessed [date]}
}
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